I wonder why they didn't use the coach battery to restart the Lithium batteries? Would probably want a switch so you only connect when needed. One less battery, reduced weight, and not faced with a difficult battery replacement in the future. Probably not as easy as I think. Just a thought.
That same question has been asked many times on here
I think there are a few reasons that would make some sense.
I think that the primary one is that would be the most important would be the other side of the charging, as in what happens if the lithium suddenly shuts down when being charged by the alternator, shore power, or solar? If those sources suddenly lose a place for their output to go, even if the field of the alternator and charging control is shut down in the solar, you can get a very big voltage spike that could take out any electronics that are connected at the time, including the alternator, Balmar, solar controller, shore charger, and anything plugged into 12v in the van. Having the AGM there removes the chance of that happening. If the batteries are in cold shutdown the starting battery would have to stay on until the heaters allowed the lithium to come back on, which can be a while, so you would have to hold a button that long or have it on a timer.
Having the starting battery in the circuit all the time would violate a lot of new vehicle charging rules related to the computer controls and would also allow the starting battery to be accidentally discharged.
The AGM was a quick and effective way to handle the issue when they had all kinds of recovery issues, and probably some shutdown issues also as they did have a bunch of Balmar failures also (of course we still hear of quite a few of them now also).
ARV did not use an alternate 12v battery in their lithium setup and would use the residual power in the lithium bank to activate charging sources, which worked fine unless the batteries were in cold shutdown and you would have to get some external heat to the batteries to get them back online. They must have had a relatively foolproof shutdown of the lithiums that would shut off the field of the alternator and the charging sources ahead of the lithiums actually going offline, I think.
I don't think we have ever heard yet how Volta is doing it.