Well, remember that we have a DC-AC-DC setup, so the Multiplus thinks it is on shore power (I have the AC input limited to 13A, which is how you control the draw from the engine alternator. This is conservative, but good enough for now). Also, with the Transit's dual alternator, I get full power from the alternator even at idle. This turns out to be the main virtue of the Transit dual alternator scheme.
I am thinking that with Home Assistant controlling things, I will just write a little script that will monitor SOC and simply turn off charging at the setpoint, and turn it back on below some hysteresis point. Maybe it isn't that simple, but seems like a good place to start.
Your charge rate is actually pretty close to what we have only we would have higher DC amps and lower voltage on the DC side as you do. We charge at a bit over 120 amps at 13.7v and by the time you add a bit of inefficiency for the DC-AC-DC units our watts are probably pretty close.
You are seeing the benefits of parallel alternators that I always liked in the past with all out previous systems. No hot alternators alternators at idle with two big ones running unless you are using a bunch of power for something else besides. Unfortunately, I couldn't get parallel to work with Wakespeed and lithium do to the equipment limitations and the necessity of being able to turn off coach charging. Does the V6 get any rougher running at idle with full output? With 6.0 in our van, which has very low 545rpm idle, I could just feel it a bit. Now we we power shape and have about 60 amps at idle and the alternator is very happy and can't feel it at all in the engine running.
You may not have to use Home Assistant on your system as it appears they have the equivalent of the Victron battery monitor in the components somplace, based on the history and settings you have shown. We are using the built SOC based internal relay to turn on and off the charging at settable points, so you may well be able to do the same thing. You would be controlling your current charge on and off relays in the system, though, I think, and wouldn't need a built in one which probably isn't there in your system's monitor.