Depends critically about the details of your rig. Assuming your hot water heater is a storage type (as opposed to on-demand), it obviously won't freeze if you keep it operating for the duration of your trip.
Tanks are rarely damaged due to freezing, as long as they are not kept completely full. Also, adding heat pads is an easy upgrade and good insurance. Your black and gray tanks and macerator can be protected by adding antifreeze during use.
PEX pipes are quite robust to freezing. Plastic valves and fittings not so much. Anything outside the van is at risk unless heated.
All of that said, a few hours over a mountain pass bracketed by above-freezing temperatures is probably not a great risk.
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Now: 2022 Fully-custom buildout (Ford Transit EcoBoost AWD)
Formerly: 2005 Airstream Interstate (Sprinter 2500 T1N)
2014 Great West Vans Legend SE (Sprinter 3500 NCV3 I4)
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