I still don't see how the grease could do that kind of problem, sorry. The link GeorgeRa put up explains it well.
My guess, strictly a guess, is that the codes you saw for the connectors was not caused by the grease but was an indicator of a problem with the connector by it's presence. Connectors commonly get intermittent as their failure mode, often due to the oxidation mentioned in the link. Simply unplugging and replugging them in will often get them to work again for a while. At that point, many mechanics like the one at the Chevy dealer will grease the connector but not clean the contacts with contact cleaner or repeated connect and disconnect the halves so the contact self clean better. Those connectors then go intermittent again and are found with grease in them, often very fresh grease. Cleaning the contacts often will fix them but sometimes the connectors need replacement if they have not been well restrained and moving around so worn internally, are severely corroded, or have been overheated from high resistance or loads.
I will say that if you have a badly oxidized contact in a connector if you add any amount of grease or lube before you clean the contact by cycling the connector and/or contact cleaner the grease can reduce the self cleaning from cycling effect a bit. Cycling with contact cleaner is probably the best thing to do before any greasing.
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