You could try bleeding off some water from the water heater to gain air cushion in the water heater.
Turn off the water pump, open a hat water faucet, then work the pressure relief valve.
If you haven't checked the anode rod(assuming a Suburban heater) in a while, instead of using the pressure valve I would remove and check the anode and do a flush out at the same time. Make sure to relieve any pressure in the water system before removing the anode rod.
Failing that, installing an accumulator will eliminate pressure spikes.
Of course, you could have a defect in the faucet...
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