Mineral wool is good insulation, fireproof, durable, but I don't think I would use it in van because the vans don't breath the walls well enough because of steel or fiberglass skins. If the mineral wool gets wet, it won't really rot, but can generate mold or rot anything else around it, and will not readily dry without good airflow through it.
I would second using a non moisture absorbing product designed for these kinds of installations.
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